An experimental study of the reactivity of the hydroxide anion in the gas phase at room temperature, and its perturbation by hydration

SD Tanner, GI Mackay…

文献索引：Tanner, Scott D.; Mackay, Gervase I.; Bohme, Diethard K. Canadian Journal of Chemistry, 1981 , vol. 59, p. 1615 - 1621

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被引用次数: 35

摘要

Flowing afterglow measurements are reported which provide rate constants and product identifications at 298±2 K for the gas-phase reactions of OH-with CH3OH, C2H5OH, CH3OCH3, CH2O, CH3CHO, CH3COCH3, CH2CO, HCOOH, HCOOCH3, CH2= C= CH2, CH3-C≍ CH, and C6H5CH3. The main channels observed were proton transfer and solvation of the OH-. Hydration with one molecule of H2O was observed either to reduce ...