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Simple and Efficient Preparation of Enantiopure Alkyl α-Hydroxyalkyl Ketones

…, T Montes, P Romea, R Rovira, F Urpi, J Vilarrasa

文献索引:Ferrero; Galobardes; Martin; Montes; Romea; Rovira; Urpi; Vilarrasa Synthesis, 2000 , # 11 p. 1608 - 1614

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被引用次数: 9

摘要

Abstract: The acylation reaction of organolithium reagents with pyrrolidine-derived a- benzyloxy and a-silyloxy carboxamides provides a simple and high-yielding method for the preparation of enantiopure a-benzyloxy and a-silyloxy ketones. Key words: a-benzyloxy ketones, a-silyloxy ketones, acylations, pyrrolidine amides, organolithium reagents