Reactions of 2, 2′, 5′, 2′??terfuran

…, BM Howe, JD Lehmkuhler, DC Myers

文献索引：McFarland, J. W.; Howe, B. M.; Lehmkuhler, J. D.; Myers, D. C. Journal of Heterocyclic Chemistry, 1995 , vol. 32, # 6 p. 1747 - 1750

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被引用次数: 4

摘要

Abstract Formylation of 2, 2′, 5′, 2′-terfuran (1) with N-methylformanilide and phosphorus oxychloride gave 5-formyl-2, 2′, 5′, 2′-terfuran (2) and 5, 5′-diformyl-2, 2′ 5′, 2′-terfuran (3). Reduction of 2 and 3 afforded 5-hydroxymethyl-2, 2′, 5′, 2′-terfuran (4) and 5, 5′ dihydroxymethyl-2, 2′, 5′, 2′-terfuran (5), respectively. Terfuran 1 reacted with phenylmagnesium bromide to give 5-(phenylhydroxymethyl)-2, 2′, 5′, 2′-terfuran ...