Temperature??dependent kinetics studies of the reactions of C2H5O2 and n??C3H7O2 radicals with NO

J Eberhard, CJ Howard

文献索引：Eberhard; Howard International Journal of Chemical Kinetics, 1996 , vol. 28, # 10 p. 731 - 740

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被引用次数: 33

摘要

Abstract The rate coefficients for the gas-phase reactions of C 2 H 5 O 2 and nC 3 H 7 O 2 radicals with NO have been measured over the temperature range of (201–403) K using chemical ionization mass spectrometric detection of the peroxy radical. The alkyl peroxy radicals were generated by reacting alkyl radicals with O 2, where the alkyl radicals were produced through the pyrolysis of a larger alkyl nitrite. In some cases C 2 H 5 radicals ...