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The rotationally resolved electronic spectra of several conformers of 1-hexoxy and 1-heptoxy

L Zu, J Liu, S Gopalakrishnan…

文献索引:Zu, Lily; Liu, Jinjun; Gopalakrishnan, Sandhya; Miller, Terry A. Canadian Journal of Chemistry, 2004 , vol. 82, # 6 p. 854 - 866

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被引用次数: 19

摘要

Laser-induced fluorescence excitation spectra of five vibronic bands of 1-hexoxy and three bands of 1-heptoxy have been recorded in a jet-cooled environment. Experimental values of rotational constants for both the and states and components of the spin-rotational tensor for the state were obtained by an analysis of the partially resolved rotational structure of the vibronic bands. Comparing these experimental results with quantum chemistry ...