FTIR spectroscopic study of the mechanism for the gas-phase reaction between ozone and tetramethylethylene

…, CM Savage, LP Breitenbach, MD Hurley

文献索引：Niki, H.; Maker, P. D.; Savge, C. M.; Breitenbach, L. P.; Hurley, M. D. Journal of Physical Chemistry, 1987 , vol. 91, # 4 p. 941 - 946

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被引用次数: 192

摘要

Long-path FTIR spectroscopic product studies were made of mixtures containing part-per- million concentrations of O3 and (CH3), C= C (CH3),(TME) in 700 Torr of Oz-N, to determine the formation and reactions of the dimethyl-substituted Criegee intermediate (CH3), CO0 expected from O3+ TME-(CH3), CO0+(CH3), C= 0. The observed stoichiometry, A-[TME]/A [03], was typically 1.7, and among the products were CO, CO,, HCHO, CH30H, CH300H, ...