Thermal stability of peroxynitrates

F Kirchner, A Mayer–Figge, F Zabel…

文献索引：Kirchner; Mayer-Figge; Zabel; Becker International Journal of Chemical Kinetics, 1999 , vol. 31, # 2 p. 127 - 144

全文：HTML全文

被引用次数: 67

摘要

Abstract Peroxynitrates are thermally unstable intermediates (at ambient temperatures) in the atmospheric degradation of hydrocarbons. In this work, thermal lifetimes of nine peroxynitrates have been measured as a function of temperature and, for two of them, also, as a function of total pressure. In the presence of excess NO, relative concentrations of the peroxynitrates were followed in a 420 I reaction chamber as a function of time by means of ...