Polyhedron

Investigations into bis (triphenylphosphine) copper (I) complexes with cyclic derivatives of methylpyruvate thiosemicarbazones

M Belicchi-Ferrari, F Bisceglie, E Buluggiu, G Pelosi…

文献索引：Belicchi-Ferrari, Marisa; Bisceglie, Franco; Buluggiu, Enrico; Pelosi, Giorgio; Tarasconi, Pieralberto Polyhedron, 2010 , vol. 29, # 10 p. 2134 - 2141

全文：HTML全文

被引用次数: 1

摘要

The syntheses of four compounds, obtained by the reaction of methylpyruvate thiosemicarbazone (Hmpt) and its methyl (Me-Hmpt) and allyl (Allyl-Hmpt) derivatives with bis (triphenylphosphine) copper (I) acetate, are reported. The compounds [Cu (PPh3) 2 (ptc)(Hptc)]· H2O (1),[Cu (PPh3) 2 (Me-ptc)](2),[Cu2 (PPh3) 2μ-S (Me-pt) μ-S (Me-ptc)]· H2O (3) and [Cu (PPh3) 2 (Allyl-ptc)](4)[H2pt= pyruvic acid thiosemicarbazone and Hptc= ...