Tetrahedron letters

tert-Butyldimethylsilyldichloromethyllithium as a dichloromethylene dianion synthon. 1, 3-rearrangement of silyl group from carbon to oxide

H Shinokubo, K Miura, K Oshima, K Utimoto

文献索引：Shinokubo, Hiroshi; Miura, Katsukiyo; Oshima, Koichiro; Utimoto, Kiitiro Tetrahedron Letters, 1993 , vol. 34, # 12 p. 1951 - 1954

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被引用次数: 41

摘要

... 15; A typical experiment is as follows. A THF (2 ml) solution of tert-butyldimethyl( dichloromethyl)silane (0.24 g, 1.2 mmol) was added to a solution of. 16; The products consist of two monosilyl ethers such as PhCH(OH)CCl 2 CH(OSiMe 2 -t-Bu)C 6 H 4 OMe and PhCH(OSiMe 2 -t-Bu)CCl 2 CH(OH). 17; K. Miura, Y. Ichinose, K. Nozaki, K. Fugami, K. Oshima, K. Utimoto; Bull. Chem. Soc. Jpn., 62 (1989), p. 143. ...