Tetrahedron

A new synthetic approach for functional triisopropoxyorganosilanes using molecular building blocks

Y Maegawa, M Waki, A Umemoto, T Shimada…

文献索引：Maegawa, Yoshifumi; Waki, Minoru; Umemoto, Akinari; Shimada, Toyoshi; Inagaki, Shinji Tetrahedron, 2013 , vol. 69, # 26 p. 5312 - 5318

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被引用次数: 6

摘要

We report an efficient synthetic approach for well-designed organic-bridged alkoxysilanes, which allow the formation of highly functional organosilica hybrids under mild sol–gel conditions. A series of molecular building blocks containing a triisopropoxysilyl group were synthesized and used in cross-coupling reactions. The triisopropoxysilyl group showed a good tolerance for various organic transformations. 1, 4-Diketo-3, 6-dithienylpyrrolo [3, 4-c ...