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Tetrahedron

An NBD-based colorimetric and fluorescent chemosensor for Zn 2+ and its use for detection of intracellular zinc ions

Z Xu, GH Kim, SJ Han, MJ Jou, C Lee, I Shin, J Yoon

文献索引:Xu, Zhaochao; Kim, Gun-Hee; Han, Su Jung; Jou, Min Jung; Lee, Chongmok; Shin, Injae; Yoon, Juyoung Tetrahedron, 2009 , vol. 65, # 11 p. 2307 - 2312

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被引用次数: 104

摘要

A new 7-nitrobenz-2-oxa-1, 3-diazole (NBD) based colorimetric and fluorescence chemosensor for Zn2+, an ion involved in many biological processes, was designed and synthesized. The NBD-probe 1 displays a red-to-yellow color change and an enhancement of fluorescent intensity in the presence of an aqueous solution of Zn2+ ions (pH 7.2). Internal charge transfer (ICT) and photoinduced electron transfer (PET) mechanisms are ...