Journal of Physical Chemistry

Infrared multiphoton-induced isomerization of tetrafluorocyclopropene

HB Friedrich, DJ Burton, DC Tardy

文献索引：Friedrich, H. Bruce; Burton, Donald J.; Tardy, D. C. Journal of Physical Chemistry, 1987 , vol. 91, # 25 p. 6334 - 6336

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被引用次数: 6

摘要

Infrared multiphoton excitation of tetrafluorocyclopropene (TFCP) leads to the unexpected formation of tetrafluoroallene (TFA) and tetrafluoropropyne (TFP). The ratio of TFP to TFA formed in the reaction is independent of fluence and pressure, and no other products are formed. The conversion per pulse increases as the pressure of TFCP increases but decreases as the pressure of a buffer gas or the products increases. The apparent ...