The Journal of Physical Chemistry

Multiphoton excitation of trifluoroethene. Allene production by difluorovinylidene

RA Stachnik, GC Pimentel

文献索引：Stachnik, Robert A.; Pimentel, George C. Journal of Physical Chemistry, 1984 , vol. 88, # 11 p. 2205 - 2210

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被引用次数: 4

摘要

Trifluoroethene was excited with a high-power, pulsed C02 laser, and the products were analyzed by mass and infrared spectroscopy. Mainly, this initiates aa elimination of HF to produce difluorovinylidine, CCF2. This species adds across the double bond of another parent molecule followed by deactivation or release of CF, and carbon insertion to produce trifluoroallene and C2F4. In the presence of other olefins, CzH4, C2D4, and C2F4, multiphoton excitation of ...