t-Butylsilicon Compounds1, 2

LJ Tyler, LH Sommer, FC Whitmore

文献索引：Tyler; Sommer; Whitmore Journal of the American Chemical Society, 1947 , vol. 69, p. 981 Journal of the American Chemical Society, 1948 , vol. 70, p. 2877

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被引用次数: 40

摘要

Summary 1. Ethyl trimethylsilylacetate has been synthesized from ethyl chloroformate and the Grignard reagent of chloromethyltrimethylsilane. 6 2. Reagents such as dilute, hot hydrochloric acid, dilute alkali, hydrogen chloride gas, bromine and hot absolute ethanol cleave the Si-C bond of this ester.