e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
t-Butylsilicon Compounds1, 2
LJ Tyler, LH Sommer, FC Whitmore
Index: Tyler; Sommer; Whitmore Journal of the American Chemical Society, 1947 , vol. 69, p. 981 Journal of the American Chemical Society, 1948 , vol. 70, p. 2877
Summary 1. Ethyl trimethylsilylacetate has been synthesized from ethyl chloroformate and the Grignard reagent of chloromethyltrimethylsilane. 6 2. Reagents such as dilute, hot hydrochloric acid, dilute alkali, hydrogen chloride gas, bromine and hot absolute ethanol cleave the Si-C bond of this ester.
