The Journal of Organic Chemistry

The addition of silicon hydrides to olefinic double bonds. x. addition to phenylalkenes. the nuclear magnetic resonance proton spectra of (phenylalkyl) silanes

MC Musolf, JL Speier

文献索引：Musolf,M.C.; Speier,J.L. Journal of Organic Chemistry, 1964 , vol. 29, p. 2519 - 2524

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被引用次数: 61

摘要

The addition of certain silicon hydrides to phenylalkenes of the formula Ph (CHz), CH= CHz (I) or PhCH= CH (CHZ), H (11)(n= 0 to 4) with chloroplatinic acid as the catalyst leads in each case to two products: A, Ph (CH2),+, SiMe, Y3-., and C, PhCH (SiMe, Y3-.)(CH~).+ 1H. Examples were studied with Y= C1, F, or Me3Si0 and z= 0, 1, 2, or 3. The relative amounts of A to C in each case depends upon the nature of Y and the values of z and n. Substituents ...