Mass spectroscopy of organosilicon compounds. Examples of interaction of the silyl center with remote phenyl groups

WP Weber, AK Willard, HG Boettger

文献索引：Weber,W.P. et al. Journal of Organic Chemistry, 1971 , vol. 36, p. 1620 - 1626

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被引用次数: 24

摘要

Mass spectroscopy is a particularly powerful analytical method of structure determination. The occurrence of molecular rearrangements of ions, often with concurrent fragmentation, in the mass spectrometer complicates the determination of the original structure. Certainly such rearrangements must be recognized if fragment ions are to provide useful structural data. Two major types of rearrangements involving silyl centers have been observed. The first ...