Dehydration of n-butanol on zeolite H-ZSM-5 and amorphous aluminosilicate: detailed mechanistic study and the effect of pore confinement

MA Makarova, EA Paukshtis, JM Thomas, C Williams…

文献索引：Makarova, M. A.; Paukshtis, E. A.; Thomas, J. M.; Williams, C.; Zamaraev, K. I. Journal of Catalysis, 1994 , vol. 149, # 1 p. 36 - 51

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被引用次数: 79

摘要

Abstract This study of the catalytic dehydration of n-butanol on zeolite H-ZSM-5 and amorphous aluminosilicate confirms the reaction scheme proposed earlier by the authors for isobutanol dehydration. The rate constant for n-butanol dehydration on H-ZSM-5 (determined from in situ FTIR kinetic studies by monitoring the growth of the water deformation peak at 1640 cm− 1) is shown to be the true dehydration rate constant (1.7× ...