The Cleavage of Sulfides and Sulfones by Alkali Metals in Liquid Amines. 1 I

WE Truce, DP Tate, DN Burdge

文献索引：Truce,W.E. et al. Journal of the American Chemical Society, 1960 , vol. 82, p. 2872 - 2876

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被引用次数: 73

摘要

Reductive cleavages using sodium in liquid ammonia have been reported for both ethers and sulfides. Diaryl ethers are reported to give the corresponding phenol and aromatic hydrocarbon with the unsymmetrical diaryl ethers cleaving in the direction which gives the weakest a~ id.~.~ Alkyl aryl ethers are cleaved in poor yields to the phenol and alkane,? while dialkyl ethers are unaffected. Lower molecular weight sulfides have been cleaved ...