Catalysis Today

Catalytic activity of metal organic framework Cu 3 (BTC) 2 in the cycloaddition of CO 2 to epichlorohydrin reaction

EE Macias, P Ratnasamy, MA Carreon

文献索引：MacIas, Eugenia E.; Ratnasamy, Paul; Carreon, Moises A. Catalysis Today, 2012 , vol. 198, # 1 p. 215 - 218

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被引用次数: 25

摘要

We demonstrate the novel, catalytic activity of metal organic framework of Cu3 (BTC) 2 catalysts in the synthesis of chloropropene carbonate from CO2 and epichlorohydrin. The catalysts display moderate epoxide conversions, and moderate selectivities to chloropropene carbonate at 100° C. No solvents or co-catalysts were required. It is suggested that Lewis acid copper (II) sites in the Cu3 (BTC) 2 framework promoted the ...