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Effect of acyl chain length on selective biocatalytic deacylation on O-aryl glycosides and separation of anomers

N Aggarwal, A Arya, D Mathur, S Singh, A Tyagi…

文献索引:Aggarwal, Neha; Arya, Anu; Mathur, Divya; Singh, Sukhdev; Tyagi, Abhilash; Kumar, Rajesh; Rana, Neha; Singh, Rajendra; Prasad, Ashok K. Bioorganic Chemistry, 2014 , vol. 53, p. 83 - 91

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被引用次数: 3

摘要

Abstract It has been demonstrated that Lipozyme® TL IM (Thermomyces lanuginosus lipase immobilised on silica) can selectively deacylate the ester function involving the C-5′ hydroxyl group of α-anomers over the other acyl functions of anomeric mixture of peracylated O-aryl α, β-D-ribofuranoside. The analysis of results of biocatalytic deacylation reaction revealed that the reaction time decreases with the increase in the acyl chain ...