Concerted and nonconcerted pathways for thermal conversions of deuterium-labeled cyclohexenes to butadienes and ethylenes

…, G Rauscher, J Rodriguez, JE Baldwin

文献索引：Lewis, David K.; Brandt, Benjamin; Crockford, Lisa; Glenar, David A.; Rauscher, Grant; Rodriguez, Julio; Baldwin, John E. Journal of the American Chemical Society, 1993 , vol. 115, # 25 p. 11728 - 11734

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被引用次数: 16

摘要

Diels-Alder provide vast synthetic versatility, for they are highly stereoselective and are responsive kinetically and regiochemically to substituent effects and reaction conditions. Retro-Diels-Alder reactions (retrodiene reactions) also have substantial synthetic~ tility.~ Depending on the full array of substituents and the reaction conditions, the mechanism of a particular Diels-Alder or retro-Diels-Alder reaction may be considered concerted or to ...