Synthesis of Functionalized Vinylgermanes through a New Ruthenium??Catalyzed Coupling Reaction

B Marciniec, H Ławicka, M Majchrzak…

文献索引：Marciniec, Bogdan; Lawicka, Hanna; Majchrzak, Mariusz; Kubicki, Maciej; Kownacki, Ireneusz Chemistry - A European Journal, 2006 , vol. 12, # 1 p. 244 - 250

全文：HTML全文

被引用次数: 33

摘要

Abstract Vinyl-substituted germanes react stereo-and regioselectively with olefins in the presence of complexes containing Ru [BOND] H and Ru [BOND] Ge bonds with the formation of functionalized vinylgermanes that cannot be synthesized by olefin cross- metathesis procedures. The reaction opens a new catalytic route for preparation of a class of organogermanes that are potent organometallic reagents for organic synthesis because ...