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The Hydrogenation of Substituted Acetylenes with Raney Nickel

KN Campbell, MJ O'Connor

文献索引:Campbell; O'Connor Journal of the American Chemical Society, 1939 , vol. 61, p. 2899

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被引用次数: 37

摘要

Other workers have shown that the course of the catalytic hydrogenation of substituted acetylenes is profoundly influenced both by the nature of the substituents and by the catalyst employed. With platinum catalysts, 2 in general, there is no change in the velocity of hydrogenation when two atoms of hydrogen have been absorbed, while with the less active palladium catalysts, 2~ 3 there is frequently a great diminution in velocity, and it is ...