Reactivity of Organocerium Compounds with Allyl Alcohols

R Dalpozzo, A De Nino, A Tagarelli…

文献索引：Dalpozzo, Renato; De Nino, Antonio; Tagarelli, Antonio; Bartoli, Giuseppe; Bellucci, M. Cristina; Bosco, Marcella; Sambri, Letizia Journal of Organic Chemistry, 1998 , vol. 63, # 25 p. 9559 - 9560

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被引用次数: 5

摘要

We were recently interested in the reactivity of electrophiles with organocerium reagents: 1 inexpensive, nontoxic, and nonbasic organometallic reagents introduced in the 1980s. 2 These reagents show low basicity and high nucleophilicity as opposed to organolithium and Grignard reagents; 2b therefore, they can be used with enolizable substrates (eg, benzyl ketones, 2a phosphinoyl ketones, 1c enaminones1e, g). However, they have never been ...