Tetrahedron letters

New phosphorylating agents for general synthesis of mixed phosphate esters

T Nagamatsu, T Kunieda

文献索引：Nagamatsu, Tomohisa; Kunieda, Takehisa Tetrahedron Letters, 1987 , vol. 28, # 21 p. 2375 - 2378

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被引用次数: 13

摘要

Abstract An effective procedure has been developed for the general synthesis of mixed alkyl or aryl phosphate esters by metal-catalyzed phosphorylation of alcohols with aryl bis (2-oxo- 3-oxazolinyl) phosphinate. Among metallic acetylacetonates examined as catalysts, the zirconium complex was the most effective as in activity order of Zr (IV)> Ce (III)> Zn (II)> Mn (III)> Mn (II)-complexes.