Layered double hydroxides as supported anionic reagents. Halide-ion reactivity in zinc chromium hexahydroxide halide hydrates [Zn2Cr (OH) 6X. nH2O](X= Cl, I)

KJ Martin, TJ Pinnavaia

文献索引：Martin, Kevin J.; Pinnavaia, Thomas J. Journal of the American Chemical Society, 1986 , vol. 108, p. 541 - 542

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被引用次数: 86

摘要

Several new families of heterogeneous catalysts recently have been synthesized by intercalating metal ions and cationic metal complexes between the negatively charged layers of smectite clay A complementary class of layered compounds exist in which the charge on the layers and gallery ions is the reverse of that found for smectite clays. These are the layered double hydroxides (LDH's) of the type [M," M,"'(OH) 2 (++ V)] A,,,.