Nucleophilic catalysis of the iodine–zinc exchange reaction: preparation of highly functionalized diaryl zinc compounds

…, M Dochnahl, P Knochel

文献索引：Kneisel, Florian F.; Dochnahl, Maximilian; Knochel, Paul Angewandte Chemie - International Edition, 2004 , vol. 43, # 8 p. 1017 - 1021

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被引用次数: 142

摘要

Halogen–metal exchange reactions are among the most powerful methods for preparing organometallic reagents. Pioneered by Wittig et al.[1] and Gilman et al.,[2] the halogen– lithium exchange has become an important method for the preparation of functionalized aryl and heteroaryl lithium compounds.[3] The halogen–magnesium [4] and the halogen–