Tetrahedron

Carbonylative coupling reaction of organofluorosilanes with organic halides promoted by fluoride ion and palldium catalyst

Y Hatanaka, S Fukushima, T Hiyama

文献索引：Hatanaka, Yasuo; Fukushima, Satoshi; Hiyama, Tamejiro Tetrahedron, 1992 , vol. 48, # 11 p. 2113 - 2126

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被引用次数: 85

摘要

Palladium-catalyzed carbonylative cross coupling reaction of organofluorosilanes with organic halides was achieved in the presence of fluoride ion and an atmospheric pressure of carbon monoxide. Alkenyl-or arylfluorosilanes effectively underwent this reaction with alkenyl or aryl iodides in moderate to good yields. Thus, highly functionalized ketones are readily available without protection of reactive functional group such as aldehyde, ketone, ...