The Journal of Organic Chemistry

4-Thiazoline-2-thiones. I. The Structure of intermediate 4-hydoxythiazolidine-2-thiones

WJ Humphlett, RW Lamon

文献索引：Humphlett,W.J.; Lamon,R.W. Journal of Organic Chemistry, 1964 , vol. 29, p. 2146 - 2148

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被引用次数: 22

摘要

The infrared absorption spectrum of the intermediate isolated from reaction of ammonium dithiocarbamate and chloroacetone does not support a dithiocarbamate structure. Absorption bands expected in the 5.8-and 8-p regions attributed to a ketone C= O group are missing.-4 band near 3.00 p indicates the presence of the OH group, however, required by structure I. Disappearance of the C= O band of an intermediate dithiocarbamate was ...