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Understanding the Structural Properties of a Homologous Series of Bis??diphenylphosphine Oxides

P Calcagno, BM Kariuki, SJ Kitchin…

文献索引:Calcagno, Patrizia; Kariuki, Benson M.; Kitchin, Simon J.; Robinson, James M. A.; Philp, Douglas; Harris, Kenneth D. M. Chemistry - A European Journal, 2000 , vol. 6, # 13 p. 2338 - 2349

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被引用次数: 46

摘要

Abstract A homologous series of bis-diphenylphosphine oxides (C 6 H 5) 2 PO (CH 2) n PO (C 6 H 5) 2 (with n= 2–8; denoted 2-8] have been investigated to explore the effects of a range of competing and cooperative intermolecular and intramolecular interactions on the structural properties in the solid state. The important factors influencing the structural properties include intramolecular aspects such as the conformation of the aliphatic chain ...