Kinetic Study of the Reactions of Chlorine Atoms and Cl2-Radical Anions in Aqueous Solutions. 1. Reaction with Benzene

…, M Geronés, JA Rosso, SG Bertolotti…

文献索引：Martire; Bertolotti; Braun; Gonzalez; Alegre; Gerones; Rosso Journal of Physical Chemistry A, 2000 , vol. 104, # 14 p. 3117 - 3125

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被引用次数: 74

摘要

The photolysis of Na2S2O8 aqueous solutions containing Cl-ions is a clean method for kinetic studies of the species Cl/Cl2-in the absence and presence of added aromatic substrates. Laser and conventional flash-photolysis techniques were employed to investigate the aqueous phase reactions of chlorine atoms and Cl2-(340 nm) radical ions in the presence and absence of benzene. A mechanism is proposed which accounts for the ...