Highly selective oxidation of allylic alcohols catalysed by monodispersed 8-shell Pd nanoclusters in the presence of molecular oxygen

…, T Akita, T Mizugaki, K Ebitani, K Kaneda

文献索引：Choi, Kwang-Min; Akita, Tomoki; Mizugaki, Tomoo; Ebitani, Kohki; Kaneda, Kiyotomi New Journal of Chemistry, 2003 , vol. 27, # 2 p. 324 - 328

全文：HTML全文

被引用次数: 57

摘要

Treatment of Pd4phen2 (CO) 2 (OAc) 4 with metal nitrates such as Cu (NO3) 2 produced monodispersed Pd nanoclusters with a mean diameter and standard deviation (d±σ) of 38±2.1 Å (σ/d= 6%). The Pd nanoclusters act as heterogeneous catalysts for the selective oxidation of primary aromatic allylic alcohols using molecular oxygen as an oxidant. This unique catalysis can be ascribed to multiple interactions between the alcohol and specific ...