Polyethylene as a nonvolatile solid cosolvent phase for catalyst separation and recovery
Y Yang, N Priyadarshani, T Khamatnurova…
文献索引：Yang, Yanfei; Priyadarshani, Nilusha; Khamatnurova, Tatyana; Suriboot, Jakkrit; Bergbreiter, David E. Journal of the American Chemical Society, 2012 , vol. 134, # 36 p. 14714 - 14717,4
The studies described here show that a relatively low molecular weight, narrow polydispersity polyethylene (PE) wax (Polywax) can serve as a nontoxic and nonvolatile alternative to alkane solvents in monophasic catalytic organic reactions where catalysts and products are separated under biphasic conditions. In this application, a polymer that is a solid at room temperature substitutes for a conventional alkane solvent at ca. 80° C. In ...
