Organic letters

Cu-Catalyzed C (sp3)–H Bond Activation Reaction for Direct Preparation of Cycloallyl Esters from Cycloalkanes and Aromatic Aldehydes

J Zhao, H Fang, J Han, Y Pan

文献索引：Zhao, Jincan; Fang, Hong; Han, Jianlin; Pan, Yi Organic Letters, 2014 , vol. 16, # 9 p. 2530 - 2533

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被引用次数: 37

摘要

Cu-catalyzed dehydrogenation–olefination and esterification of C (sp3)–H bonds of cycloalkanes with TBHP as an oxidant has been developed. The reaction involves four C–H bond activations and gives cycloallyl ester products directly from cycloalkanes and aromatic aldehydes.