Bulletin of the Chemical Society of Japan

Vibrational Level Populations of Hydrogen Fluoride Produced in Infrared Multiple-photon Decompositon of C 2 H 5 F

Y Ishikawa, S Arai

文献索引：Ishikawa; Arai Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 8 p. 2040 - 2045

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被引用次数: 3

摘要

CO 2 TEA laser-induced photolysis of C 2 H 5 F was studied by using a time-resolved infrared fluorescence technique. Molecular elimination of vibrationally excited hydrogen fluoride (HF*) from C 2 H 5 F* occurs in the process. Rotational temperatures and vibrational level populations of HF* are estimated from observed fluorescence spectra by computational fitting. Higher vibrational levels are populated to a less extent in the decomposition under ...