Photolysis of p-toluenesulfonyl azide and its charge-transfer complex with aniline

…, RS Lenox, PA Christie, RA Shoemaker

文献索引：Hoyle, C. E.; Lenox, R. S.; Christie, P. A.; Shoemaker, R. A. Journal of Organic Chemistry, 1983 , vol. 48, # 12 p. 2056 - 2061

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被引用次数: 7

摘要

Photolysis of p-toluenesulfonyl azide (1) in p-xylene and cyclohexane gives primarily the products derived from insertion of (ptolylsulfony1) nitrene into the solvent. For p-xylene, an unstable intermediate product is formed which decomposes in the dark at room temperature to give both the ring-insertion product and the corresponding p-toluenesulfonamide (2). Photolysis of the ground-state charge-transfer complex between p-toluenesulfonyl azide ...