Dalton Transactions

Reactions of free radicals with η 3-allylpalladium (ii) complexes: phenyl and trityl radicals

SJ Reid, MC Baird

文献索引：Reid, Simon J.; Baird, Michael C. Journal of the Chemical Society. Dalton Transactions, 2003 , # 20 p. 3975 - 3980

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被引用次数: 6

摘要

The compounds (η3-allyl) PdCl (PPh3) and [(η3-allyl) Pd (PPh3) 2] Cl react with phenyl and trityl radicals generated from the thermal decomposition of phenylazotriphenylmethane (PhNNCPh3, PAT) in benzene at 60° C. The products are the palladium phenyl compounds,[PdPhCl (PPh3)] 2 and trans-PdPhCl (PPh3) 2, respectively, and 4, 4, 4- triphenyl-1-butene, the latter being the result of coupling of the trityl radical with the allyl ...