The Journal of Organic Chemistry

The Chemistry of Carbanions. VIII. The Intramolecular Alkylation of Ketyl Radical Anions1

HO House, JJ Riehl, CG Pitt

文献索引：House,H.O. et al. Journal of Organic Chemistry, 1965 , vol. 30, p. 650 - 653

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被引用次数: 7

摘要

Consequently, we have been unable to find reaction conditions which permit the desired cyclization reaction (ie., 1+ 4) to predominate over bond cleavage to form acyclic products (eg, 1-t 5). Since available half-wave potential measurements6 suggest that formation of the ketyl 2 should be energetically favored over direct carbon-chlorine bond cleavage (ie., la or lb 3 6), our results imply that the acyclic products 5 isolated have been derived, at least in ...