前往化源商城

Journal of Organometallic Chemistry

Product distribution in the metalation of some aromatic substrates with n-butyllithium

DA Shirley, JR Johnson, JP Hendrix

文献索引:Shirley,D.A. et al. Journal of Organometallic Chemistry, 1968 , vol. 11, p. 209 - 216

全文:HTML全文

被引用次数: 68

摘要

Abstract The following compounds were metalated with n-butyllithium in ether and product isomer ratios determined with the aid of vapor phase chromatographic techniques: anisole, trifluoromethylbenzene, phenetole, m-cresol methyl ether, resorcinol dimethyl ether and biphenyl. The data with all substrates except biphenyl are in accord with the view of relative rate of attack of different ring positions controlled by inductive effects of ring substituent on ...