Journal of the American Chemical Society

Azomethine Chemistry. II. Formation of Peptides from Oxazolidine-5-ones

RG Hiskey

文献索引：Hiskey,R.G.; Jung,J.M. Journal of the American Chemical Society, 1963 , vol. 85, p. 578 - 582

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被引用次数: 22

摘要

In an earlier report'model compounds resembling the azomethine intermediate I1 in the pyridoxal-catalyzed transamination reaction were generated and catalytically hydrogenated. The addition of hydrogen was shown to proceed stereospecifically and afford optically active a-amino acids from the corresponding a-keto acid. In order to obtain a more complete understand-