The Journal of Organic Chemistry

Functionalized organolithium reagents. 8. Novel (. alpha.,. beta.-epoxyalkyl) lithium reagents via the lithiation of organyl-substituted epoxides

JJ Eisch, JE Galle

文献索引：Eisch, John J.; Galle, James E. Journal of Organic Chemistry, 1990 , vol. 55, # 16 p. 4835 - 4840

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被引用次数: 64

摘要

Results Organyl-Substituted Epoxides. In order to investigate the acidifying character of various organic groups CY to the epoxide linkages (R" in eq 2), the compounds depicted in Scheme I were subjected to the action of the 1: l complex of tert-butyllithium and TMEDA at temperatures of-80 to-115 OC.' After a suitable interval the reaction