Luminescent Cyclometalated Dialkynylgold (III) Complexes of 2??Phenylpyridine??Type Derivatives with Readily Tunable Emission Properties

…, KMC Wong, N Zhu, VWW Yam

文献索引：Au, Vonika Ka-Man; Wong, Keith Man-Chung; Zhu, Nianyong; Yam, Vivian Wing-Wah Chemistry - A European Journal, 2011 , vol. 17, # 1 p. 130 - 142

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被引用次数: 57

摘要

Abstract A novel class of luminescent dialkynylgold (III) complexes containing various phenylpyridine and phenylisoquinoline-type bidentate ligands has been successfully synthesized and characterized. The structures of some of them have also been determined by X-ray crystallography. Electrochemical studies demonstrate the presence of a ligand- centered reduction originating from the cyclometalating C^ N ligand, whereas the first ...