Tetrahedron

The vapour phase fluorination of trichloroethylene with cobalt trifluoride and with manganese trifluoride

G Fuller, M Stacey, JC Tatlow, CR Thomas

文献索引：Fuller,G. et al. Tetrahedron, 1962 , vol. 18, p. 123 - 133

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被引用次数: 15

摘要

Reactions with cobaltic fluoride and with manganic fluoride have been used for the addition of fluorine to trichloroethylene and the ranges of products identified. With manganic fluoride the main one was 1, 1, 2-trichloro-1, 2-difluoroethane. Upon dechlorination this yielded chloro-1, 2-difluoroethylene which in some respects did not behave as a typical highly- fluorinated olefin. It was separated into cis-and trans-isomers and its bromine and iodine ...