Journal of fluorine chemistry

The chlorination of 1, 2-difluoroethane (HFC-152)

MJ Nappa, AC Sievert

文献索引：Nappa, Mario J.; Sievert, Allen C. Journal of Fluorine Chemistry, 1993 , vol. 62, # 2-3 p. 111 - 118

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被引用次数: 1

摘要

Abstract The photochlorination of CH 2 FCH 2 F yields CH2FCC1 2 F and CHClFCHClF, both of whichwere considered to be potential replacements for CFC-113 (CCI 2 FCF 2 Cl) based on theirboiling points (48 C and 59 C, respectively). The CHClFCHClF/CH 2 FCCl 2 F ratio canbe controlled by the choice of solvents. In aromatic solvents, the reactivity of the chlorineradical is reduced, increasing the amount of CH 2 FCCl 2 F produced. Relative ...