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Palladium Nanoclusters Supported on Propylurea??Modified Siliceous Mesocellular Foam for Coupling and Hydrogenation Reactions

N Erathodiyil, S Ooi, AM Seayad, Y Han…

文献索引:Erathodiyil, Nandanan; Ooi, Samuel; Seayad, Abdul M.; Han, Yu; Lee, Su Seong; Ying, Jackie Y. Chemistry - A European Journal, 2008 , vol. 14, # 10 p. 3118 - 3125

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被引用次数: 87

摘要

Abstract This paper describes the synthesis, characterization and applications of palladium (Pd) nanoparticles supported on siliceous mesocellular foam (MCF). Pd nanoparticles of 2– 3 nm and 4–6 nm were used in reactions involving molecular hydrogen (such as hydrogenation of double bonds and reductive amination), transfer hydrogenation of ketones and epoxides, and coupling reactions (such as Heck and Suzuki reactions). They ...