Tetrahedron letters

Organometallic reactions in aqueous media: the allylations of carbonyl compounds mediated in Zn/CdSO 4 and Zn/SnCl 2 bimetal systems

C Zhou, Y Zhou, J Jiang, Z Xie, Z Wang, J Zhang, J Wu…

文献索引：Zhou, Cunliu; Zhou, Yuqing; Jiang, Jiaoyang; Xie, Zhen; Wang, Zhiyong; Zhang, Jiahai; Wu, Jihui; Yin, Hao Tetrahedron Letters, 2004 , vol. 45, # 28 p. 5537 - 5540

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被引用次数: 22

摘要

Zn/CdSO4 and Zn/SnCl2 bimetal systems were employed in the allylations of aldehydes or ketones in distilled water to afford the corresponding homoallylic alcohols in good yields. Also, the chemoselectivity was studied under the same condition. It was found that good chemoselectivity of allylations could be obtained for different carbonyl compounds under the mediation of our bimetal systems.