Total synthesis of pseudomonic acid C

GE Keck, DF Kachensky, EJ Enholm

文献索引：Keck, Gary E.; Kachensky, David F.; Enholm, Eric J. Journal of Organic Chemistry, 1984 , vol. 49, # 8 p. 1462 - 1464

全文：HTML全文

被引用次数: 18

摘要

IC A key element of the synthetic strategy detailed below is recognition of the structure of (+)-pseudomonic acid C as that of a highly modified L-lyxose, a commercially available sugar. Thus the synthetic planning may be re- duced to the synthesis of the requisite "upper" and "lower" appendages for incorporation at C1 and C4, respectively, coupled with appropriate means for their stereocontrolled introduction. In this context, it should be noted that the C5 ...