The Journal of Organic Chemistry

Long-range effects in the alkylation of benzene with dichloroalkanes

DL Ransley

文献索引：Ransley,D.L. Journal of Organic Chemistry, 1968 , vol. 33, p. 1517 - 1522

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被引用次数: 4

摘要

The results obtained from alkylation reactions on benzene with two series of primary chloro- containing dichloroalkanes are interpreted on the basis of a long-range effect of the reference primary chloro group on the reaction of the second chloro group. Benzene was alkylated with 1, Xdichlorooctane (Le., a mixture of the 1, 1 through 1, s isomers) using a boron trifluoride-hydrogen fluoride catalyst (a system specific for alkylation of secondary ...