The synthesis and deep purification of GaEt 3. Reversible complexation of adducts MAlk 3 (M= Al, Ga, In; Alk= Me, Et) with phenylphosphines

…, AA Korlyukov, AV Lebedev, VD Sheludyakov…

文献索引：Shatunov; Korlyukov; Lebedev; Sheludyakov; Kozyrkin; Orlov, V.Yu. Journal of Organometallic Chemistry, 2011 , vol. 696, # 10 p. 2238 - 2251

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被引用次数: 11

摘要

Optimal parameters of organomagnesium technique of synthesis of triethylgallium have been defined. Various techniques of deep purification of triethylgallium to the extent required in metalorganic vapor-phase epitaxy MOVPE have been studied: by way of residue ether displacement through high-performance rectification and interaction with high pure aluminum and gallium trichloride, and by way of reversible complexation with ...